Both FL and ML are assassins and hide their identity in the first part of their marriage. They both work for the same organization and FL is tasked with killing ML which she thinks the easiest way to accomplish is to marry him and thereby entering his mansion. It is also a romance since the two of them fall in love with each other.
If you enjoy these bite-sized costume dramas but trying to sort through the gems from the rubbish, A Familiar Stranger is among the best of the genre. Like My Decoy Bride, one of the main characters recognize the other from a past encounter, and while the circumstances that lead to the marriage are different, the FL also has a false identity when she marries the ML.